Journal of Organometallic Chemistry p. C4 - C6 (1993)
Update date:2022-08-12
Topics:
Schenk, Wolfdieter A.
Stubbe, Michael
Gas phase pyrolysis (500-600 deg C, 1 s) of 1-phenyl-3-arsolene, 1-phenyl-3-methyl-3-arsolene, and 1-phenyl-3,4-dimethyl-3-arsolene gives polymeric (PhAs)x and its corresponding diene.Upon increasing the temperature, further decomposition to elemental arsenic and a mixture of aromatic hydrocarbons can be observed.If the pyrolysis is carried out with a large excess of butadiene or dimethylbutadiene, significant amounts of phenylarsinidene transfer products are formed.
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