A NEW CLASS OF CLUSTER COMPLEXES BETWEEN GROUP IB METAL ARYLACETYLIDES. PREPARATION AND X-RAY STRUCTURE OF A NOVEL TETRANUCLEAR GOLD-SILVER CLUSTER

DOI: 10.1016/0022-328X(86)80071-7

Source and publish data:

Journal of Organometallic Chemistry p. C10 - C12 (1986)

Update date:2022-08-03

Topics:

Authors:

Abu-Salah, Omar M.

Knobler, Carolyn B.

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Article abstract of DOI:10.1016/0022-328X(86)80071-7

The cluster has been prepared by the reaction of Ph3PAuC2Ph with _n and by that of Ph3P with the polymer _n.The structure of the new cluster involves a linear arrangement of two phenylacetylide groups about each gold atom, with each silver atom asymmetrically ?-bonded to two triple bonds and one phosphine ligand.

Full text of DOI:10.1016/0022-328X(86)80071-7

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