Journal of Organometallic Chemistry p. 7 - 16 (1984)
Update date:2022-08-31
Topics:
Pickles, G. M.
Spencer, T.
Thorpe, F. G.
Chopa, A. B.
Podesta, J. C.
A number of tetraaryltin compounds, Ar4Sn (where Ar = phenyl, o- and p-tolyl, and p-chlorophenyl) and tryphenyltin compounds, PH3SnX (where X = Cl, H, OH, OCOCH3 and OCOCF3) have been treated with diborane in tetrahydrofuran.Transmetallation occurs in which one or more aryl groups are transferred to boron.The organoboron intermediates give phenols upon oxidation and boronic and borinic acids upon hydrolysis.Pyridine complexes of organoboranes have also been isolated.
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