Reaction of I2 with α-boraalkylmagnesium bromide: A new synthesis of mixed alkyl secondary alcohols

DOI: 10.1016/S0040-4020(01)81907-4

Source and publish data:

Tetrahedron p. 8877 - 8886 (1993)

Update date:2022-08-11

Topics:

Authors:

Kishan Reddy

Periasamy

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)81907-4

1,1-Diborylalkanes, prepared through hydroboration of 1-alkynes using BH₃:N(C₂H₅)₂Ph complex, on reaction with Grignard reagent followed by I₂/NaOH treatment and H₂O₂/OH^- oxidation give the corresponding mixed alkyl secondary alcohols.

Full text of DOI:10.1016/S0040-4020(01)81907-4

Products guided by the article

Product name:1-phenyl-1-decanol

Cas No:106560-85-4

R&D Labs maybe for 106560-85-4

Shanghai Yudiao Chemistry Technology Co.,Ltd

Contact:0086-18964703211

Address:Building NO.5, NO.218,Rongtian Road,ganxiang town,Jinshan District,shanghai,201518,china
Hisyntech Corporation Limited

Contact:0086-22-23410962

Address:17-201, Ningfuli, Shuishanggongyuandong road,Nankai district, Tianjin, China
Nanjing Norris Pharm Technology Co., Ltd.

Contact:+86-13901585132

Address:2 Qiande Road, Jiangning sciencepark Hi-Tech Zone, Nanjing, P.R.China
Yancheng Smiling Imp & Exp Co., Ltd.

Contact:+86-515-83173586

Address:Rm1207, BLD#03, Phoenix Plaza, Juheng Road, Yancheng, Jiangsu, P.R. China
Shanghai Bocimed Pharmaceutical Co., Ltd.

website:http://www.bocimed.com

Contact:+86-21-68861632

Address:Building 1, Lane 647, Songtao Road, Zhangjiang High-Tech Park, Shanghai

Relevant to this article

Eliminations from (E)-O-Arylbenzaldehyde Oximes Promoted by Hydroxide in 60 percent aq. Dimethyl Sulphoxide. Mechanism and Transition-state Characteristics of Nitrile-forming Eliminations

Doi:10.1039/P29890000489
(1989)
Effect of Pressure on the 1,3-Dipolar Cycloaddition Reaction of Diphenyldiazomethane to Carbon-Carbon Multiple Bonds

Doi:10.1021/jo00155a021
(1983)
Doi:10.1016/S0022-328X(00)84575-1
(1971)
Hydrogenation of dimethyl malonate to 1,3-propanediol catalyzed by a Cu/SiO₂ catalyst: The reaction network and the effect of Cu⁺/Cu⁰ on selectivity

Doi:10.1039/c6nj03960j
(2017)
NOVEL RING TRANSFORMATIONS OF PYRAZINES BY INTRAMOLECULAR DIELS-ALDER REACTIONS

Doi:10.1016/S0040-4020(88)90036-1
(1988)
Elementary Reactions in the Oxidation of Alkenes.

Doi:10.1002/bbpc.19830871113
(1983)

Article Doi