Reaction of I2 with α-boraalkylmagnesium bromide: A new synthesis of mixed alkyl secondary alcohols

DOI: 10.1016/S0040-4020(01)81907-4

Source and publish data:

Tetrahedron p. 8877 - 8886 (1993)

Update date:2022-08-11

Topics:

Authors:

Kishan Reddy

Periasamy

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Article abstract of DOI:10.1016/S0040-4020(01)81907-4

1,1-Diborylalkanes, prepared through hydroboration of 1-alkynes using BH₃:N(C₂H₅)₂Ph complex, on reaction with Grignard reagent followed by I₂/NaOH treatment and H₂O₂/OH^- oxidation give the corresponding mixed alkyl secondary alcohols.

Full text of DOI:10.1016/S0040-4020(01)81907-4

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