Sulfenium Ion Promoted Polyene Cyclizations in Natural Product Synthesis. An Efficient Biomimetic-like Synthesis of (+/-) Nimbidiol

DOI: 10.1016/S0040-4039(00)99501-7

Source and publish data:

Tetrahedron Letters p. 1499 - 1502 (1989)

Update date:2022-08-17

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Authors:

Harring, Scott R.

Livinghouse, Tom

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Article abstract of DOI:10.1016/S0040-4039(00)99501-7

A four step synthesis of the modified diterpene (+/-) nimbidiol (3) from (3,4-dimethoxyphenyl)acetonitrile is described which relies on a sulfenium ion promoted polyene cyclization.A key feature of this synthesis is the one flask reductive desulfurization

Full text of DOI:10.1016/S0040-4039(00)99501-7

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