Journal of Fluorine Chemistry p. 593 - 596 (1983)
Update date:2022-08-11
Topics:
Thrasher, Joseph S.
Clifford, Alan F.
Urethanes of the type SF5NHC(O)OR react with PCl5 to give primarily SF5NCO.In only one case, where R = C6H5, was any evidence for an imine product observed.The corresponding reactions of SF5NHC(O)SR compounds give both SF5NCO and the imine product.The new compounds SF5N=C(Cl)SCH3 and SF5N=C(Cl)SC6H5 were identified by IR, NMR, and mass spectrometry.
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