Bulletin of the Chemical Society of Japan p. 1875 - 1878 (1997)
Update date:2022-08-16
Topics:
Song, Yong-Qi
Yuzuri, Tomoaki
Suezawa, Hiroko
Sakakibara, Kazuhisa
Hirota, Minoru
Nakada, Masahiro
Photolyses of 2,6- and 2,4-difluorobromobenzenes in acetonitrile gave isomerized and brominated products in addition to 1,3-difluorobenzene produced by the dehalogenation.The reactions were compared with similar reactions of the corresponding chloro- and iodoarenes.In general, photolytic cleavage of the C-X bond of 2,6-difluorohalo(X)benzene was shown to proceed more easily than the corresponding 2,4-difluorohalo compound.
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