Tetrahedron Letters p. 5639 - 5642 (1989)
Update date:2022-08-10
Topics:
Vertegaal, L. B. J.
Steeg, M. Van Der
Gen, A. Van Der
Fecapentaene-12 1 displays an unexpected reactivity when treated with hydrochloric acid in aqueous solvents.Instead of forming the unsubstituted aldehyde 2,4,6,8-dodecatetraenal 2, a completely different pathway is observed, resulting in the exclusive formation of 10-methoxy-2,4,6,8-dodecatetraenal 3a (methanol/water) or 10-hydroxy-2,4,6,8-dodecatetraenal 3b (tetrahydrofuran/water).
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