Journal of Organometallic Chemistry p. 261 - 272 (1981)
Update date:2022-08-11
Topics:
Petit, F.
Arzouyan, C.
Peiffer, G.
Gaydou, E.
At 25 deg C, and under 1 to 7 bar nitrogen pressure, the isomerization of 4-methyl-1-pentene catalyzed in benzene by CoHN2(PPh3)3 involves two active species: HCoN2(S1)(PPh3)2 and HCo(S1)(PPh3)3, respectively, in greater quantities at higher (P(N2) > 7 bars) and small quantities at P(N2) - O nitrogen pressures. The kinetic study shows that the rate of the reaction is always ruled by the equation:
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