Alumina Solid Lewis Superacid: Activated Benzene and Isomerization of Alkanes on Aluminas Chlorinated at High Temperature

DOI: 10.1039/c39890000645

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 645 - 646 (1989)

Update date:2022-08-28

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Authors:

Ayame, Akimi

Izumizawa, Takenori

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Article abstract of DOI:10.1039/c39890000645

Alumina solid Lewis superacids, prepared by high temperature chlorination of γ-alumina, activate benzene to yield a charge-transfer ?-complex and selectively isomerize cyclohexane, pentane, and butane to methylcyclopentane, 2-methylbutane, and 2-methylpropane, respectively, at 303 K.

Full text of DOI:10.1039/c39890000645

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