TRANSFORMATIONS OF ACRYLAMIDE AND POLYACRYLAMIDE AT HIGH PRESSURES AND LARGE SHEAR DEFORMATIONS

DOI: 10.1007/BF00864544

Source and publish data:

Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 944 - 949 (1992)

Update date:2022-08-11

Topics:

Authors:

Chistotina, N. P.

Zharov, A. A.

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Article abstract of DOI:10.1007/BF00864544

Radical polymerization and nucleophilic addition of an amide group to the double bond of acrylamide take place parallel in conditions of shear deformation and high pressures (up to 8 GPa). Large shear deformations cause the formation of β-alanine as the result of reactions of hydrolysis of amide groups and peptide bonds. Keywords: pressure, shear deformation, acrylamide, polyacrylamide, radical polymerization, nucleophilic addition, hydrolysis, β-alanine.

Full text of DOI:10.1007/BF00864544

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