Bulletin of the Chemical Society of Japan p. 2029 - 2030 (1984)
Update date:2022-08-11
Topics:
Tilquin, Bernard
Gourdin-Serveniere, Catherine
Miyazaki, Tetsuo
Fueki, Kenji
The dimer yields in the radiolysis of the neo-C5H12-cyclo-C5H11 (1 molpercent) mixtures at 77 and 4 K have been measured by capillary gas chromatography.Analysis of the results indicates that cyclopentyl radicals are produced selectively at 77K, while their selective formation is suppressed at 4K.This result coincides well with the data obtained by ESR spectroscopy.
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