Reductive and Regioselective Cleavage of Oxetanes Assisted by the Neighboring Hydroxyl

DOI: 10.1246/bcsj.59.1647

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1647 - 1649 (1986)

Update date:2022-08-30

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Authors:

Kato, Michiharu

Kitahara, Haruo

Yoshikoshi, Akira

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Article abstract of DOI:10.1246/bcsj.59.1647

On exposure to lithium aluminium hydride, 1,6-dioxaspiro<2.0.3.4>undecane and 5-methyl-2-oxaspiro<3.5>nonan-5-ol gave 1,2-dimethyl-c-2-(hydroxymethyl)-r-1-cyclohexanol (5) which was produced from regioselective C-O bond cleavage of oxetane rings by an int

Full text of DOI:10.1246/bcsj.59.1647

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