Formation of Dicarbonyl Compounds in the Flash Vacuum Pyrolysis of Saturated Bicyclic Peroxides

DOI: 10.1039/C39820001034

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Journal of the Chemical Society. Chemical communications p. 1034 - 1036 (1982)

Update date:2022-08-11

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Authors:

Bloodworth, A. J.

Baker, David S.

Eggelte, Henny J.

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Article abstract of DOI:10.1039/C39820001034

Under flash vacuum pyrolysis, dioxabicycloalkanes (n = 3,4, and 5) isomerise to keto-aldehydes, MeCOnCHO, whereas dioxabicycloalkanes (n = 2,3, and 4) fragment to give, by loss of hydrogen and ethylene, mixtures of cycloalkane-1,4-diones and dialdehydes, OHCnCHO.

Full text of DOI:10.1039/C39820001034

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