Tetrahedron Asymmetry p. 4437 - 4440 (2000)
Update date:2022-08-22
Topics:
Garcia Martinez, Antonio
Teso Vilar, Enrique
Garcia Fraile, Amelia
De La Moya Cerero, Santiago
Lora Maroto, Beatriz
The enantiospecific preparation of the interesting chiral source 10-hydroxycamphor from commercially available camphor is described. The synthetic procedure takes place straightforwardly in only three synthetic steps with a high overall yield. The key step of the described route is based on the ability of a 2-methylenenorbornane intermediate to undergo an enantiospecific Wagner-Meerwein rearrangement under electrophilic treatment with m-CPBA.
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