Bulletin of the Chemical Society of Japan p. 1915 - 1920 (1982)
Update date:2022-08-11
Topics:
Watanabe, Yoshihito
Numata, Tatsuo
Oae, Shigeru
In the oxygenation reaction of alkyl sulfides with Co(II)(bzacen)-O2 system, oxidative S-C bond cleavage (S-dealkylation) was found to take place exclusively.The reactivity of S-dealkylation reaction was dependent markedly on both acidity of α-methylene and steric hindrance of alkyl sulfide.The peroxo-Co(III) species is presumed to be the intermediate in this S-dealkylation reaction.
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(1982)
