A stereoselective synthetic route to (E)-α,β-unsaturated thioesters

Article abstract of DOI:10.1080/00397910008086904

Terminal alkynes 1 react with Cp₂Zr(H)Cl (Cp = η⁵-C₅H₅) and CO to give acylzirconocene chloride derivatives 2, which are trapped with arylsulfenyl chlorides to afford (E)-α,β-unsaturated thioesters.

Full text of DOI:10.1080/00397910008086904

Synthetic Communications
ISSN: 0039-7911 (Print) 1532-2432 (Online) Journal homepage: http://www.tandfonline.com/loi/lsyc20
A Stereoselective Synthetic Route To (E)-α,β-
Unsaturated Thioesters
Ping Zhong , Zhi-Xing Xiong & Xian Huang
To cite this article: Ping Zhong , Zhi-Xing Xiong & Xian Huang (2000) A Stereoselective Synthetic
Route To (E)-α,β-Unsaturated Thioesters, Synthetic Communications, 30:15, 2793-2800, DOI:
10.1080/00397910008086904
To link to this article: http://dx.doi.org/10.1080/00397910008086904
Published online: 16 Feb 2011.
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Date: 05 June 2016, At: 10:45