Baeyer-Villiger Oxidation of Bicycloheptanone to Cyclopentapyranone: a Novel Synthesis of Iridomyrmecin, Isoiridomyrmecin, and Boschnialactone

DOI: 10.1039/c39890001876

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1876 - 1878 (1989)

Update date:2022-08-23

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Authors:

Wang, Tein-Fu

Yang, Chi-Fu

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Article abstract of DOI:10.1039/c39890001876

Stereocontrolled syntheses of iridomyrmecin, isoiridomyrmecin, and boschnialactone are accomplished through a Baeyer-Villiger oxidation and either a cuprate coupling reaction or catalytic hydrogenation.

Full text of DOI:10.1039/c39890001876

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