Facile conversion of N6-benzoyladenosines into 5'-chloro-5'-deoxy-8-hydroxyadenosines by a reaction with cupric chloride: A prominent substituent effect of the N6-benzoyl group

DOI: 10.1248/cpb.39.1902

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1902 - 1904 (1991)

Update date:2022-08-05

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Authors:

Kitade Kitade

Nakanishi

Sako Sako

Hirota Hirota

Maki Maki

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Article abstract of DOI:10.1248/cpb.39.1902

Facile conversion of N⁶-benzoyl-2',3'-O-isopropylideneadenosine into N⁶-benzoyl-5'-chloro-5'-deoxy-8-hydroxy-2',3'-O-isopropylideneadenosine by a reaction with cupric chloride in acetonitrile provides a new method for the chemical modification of adenosines. This reflects the prominent substituent effect of N⁶-benzoyl group on the chemical reactivity of adenosines.

Full text of DOI:10.1248/cpb.39.1902

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