Tetrahedron p. 5451 - 5456 (1986)
Update date:2022-08-16
Topics:
Annunziata, Rita
Cinquini, Mauro
Cozzi, Franco
Raimondi, Laura
Stefanelli, Stefania
Tandem condensation of chiral α-alkoxy and α,β-dialkoxy aldehydes with allylic sulphinyl anion, and thiophile promoted desulphurization of the resulting α-substituted allylic sulphoxide afford (E)-5-alkoxy-(or 5,6-dialkoxy)-2-alkene-1,4-diols, advanced polyols precursors, the major stereochemical path occuring via a Felkin-Ahn (non chelation control) mode.
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Doi:10.1016/j.bioorg.2019.103332
(2019)Doi:10.1021/ja00246a041
(1987)Doi:10.1002/ardp.201400192
(2014)Doi:10.1248/cpb.33.3182
(1985)Doi:10.1002/ejoc.200800116
(2008)Doi:10.1021/jm00392a002
(1987)
