Tetrahedron Letters p. 7999 - 8002 (1995)
Update date:2022-08-16
Topics:
Vanni, Raffaella
Garden, Simon J.
Banks, Jeffrey T.
Ingold, Keith U.
The oxidation of 2-cyclopropylpropane by dimethyldioxirane (DMD) to 2-cyclopropylpropan-2-ol is not a free-radical chain reaction.It is suggested the free-radical chain observed by Minisci et al. when alkane/DMD reactions were carried out in the presence of CCl3Br involves H-atom abstraction from the alkane by Cl3COO. (in air) and by Me2C(O.)OCCl3 as well as by the Cl3C. radical.
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