Catalysis Communications p. 60 - 64 (2016)
Update date:2022-08-16
Topics:
Wang, Weiyan
Wu, Kui
Li, Lu
Tan, Song
Zhu, Guohua
Li, Wensong
He, Zhiqiang
Yang, Yunquan
NiSx were synthesized by microwave assisted hydrothermal method using nickel nitrate and thiourea as precursor materials. Their phase compositions were controlled by adjusting the reaction temperature and pH value. In the hydrodeoxygenation (HDO) of p-cresol on MoS2, adding NiSx enhanced the conversion but had no effect on the product distribution. NiS2 phase exhibited higher promotional effect than NiS and Ni3S4 phases. The HDO reaction mechanism for p-cresol on NiSx + MoS2 could be well explained by the Remote Control model through a migration of spillover hydrogen.
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