PHOTOCHEMICAL OXIDATION OF HYDROCARBONS BY A VANADIUM(V) PEROXO COMPLEX

DOI: 10.1007/BF00864356

Source and publish data:

Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 1502 - 1504 (1992)

Update date:2022-08-17

Topics:

Authors:

Attanasio, Donato

Suber, Lorenza

Shul'pin, G. B.

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Article abstract of DOI:10.1007/BF00864356

The oxidation of alkanes and benzene by VO(O2)L*2H2O (L = 2-picolinate) in acetonitrile is accelerated upon irradiation with visible and, especially, UV light.Cyclohexyl hydroperoxide, cyclohexanol, and cyclohexanone in approximately 2:1:1 ratio are formed from cyclohexane both in the dark and photochemical reactions.Benzene is oxidized to phenol. Keywords: oxidation, hydrocarbons, photochemistry, peroxo complexes, and vanadium.

Full text of DOI:10.1007/BF00864356

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