Journal of Organic Chemistry p. 4725 - 4726 (1994)
Update date:2022-08-29
Topics:
Maruoka, Keiji
Concepcion, Arnel B.
Yamamoto, Hisashi
Organoaluminum-promoted single homologation of aliphatic and aromatic ketones with diazoalkanes has been described, and among various organoaluminum reagents, especially bulky methylaluminum bis(2,6-di-tert-butyl-4-methylphenoxide) (MAD) is found to be highly effective for the selective homologation of various ketones.
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