Tetrahedron Letters p. 9181 - 9184 (1995)
Update date:2022-08-10
Topics:
Trofimov, Boris A.
Tarasova, Ol'ga A.
Sigalov, Mark V.
Mikhaleva, Al'bina I.
O-Propargyl ketoximes, available from the reaction of ketoximes with propargyl halides in KOH/DMSO system, readily undergo base-catalysed (t-BuOK in DMSO or THF) rearrangement to N-(1-alkenyl)acrylamides in 15-58percent yields.
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