TOTAL REACTIVITY OF PYRIDINE AND QUINOLINE VIA THE REACTIONS OF ARYLBENZOATES WITH HYDROXIDE ION. APPARENT SUBSTITUENT CONSTANS FOR SOME N-HETEROAROMATIC GROUPS

Article abstract of DOI:10.1016/S0040-4039(01)83026-4

A new set of apparent ? values was evaluated for the aza substitution of all positions in pyridyl and quinolyl groups on the basis of the alkaline hydrolysis of aryl benzoates.The enhanced reactivities of 4-pyridyloxy- and 4-quinolyloxy- groups were first estimated quantitatively.