Photoinduced Oxidation of Benzoic Acid with Aqueous Hydrogen Peroxide

DOI: 10.1039/P29800000616

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 616 - 619 (1980)

Update date:2022-08-11

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Authors:

Ogata, Yoshiro

Tomizawa, Kohtaro

Yamashita, Yukio

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Article abstract of DOI:10.1039/P29800000616

The photodecomposition of benzoic acid in aqueous hydrogen peroxide has been studied.When the ratio ₀/₀ is low, the decomposition of benzoic acid and hydrogen peroxide stops during irradiation, while at a high ₀/₀ ratio, benzoic acid is completely decomposed with cleavage of the aromatic ring.Hydroxybenzoic acid is the major product, and benzene and phenol are minor products during the initial stages of oxidation.Later lower aliphatic acids such as malonic acid appear.The probable mechanism for decomposition is discussed on the basis of product yields.

Full text of DOI:10.1039/P29800000616

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