Welcome to LookChem.com Sign In|Join Free

Article Doi

Pulse Radiolysis Study on Radical Cations of Alkyl Bromides in Aqueous Solutions

DOI: 10.1039/ft9938900477

Source and publish data:

Journal of the Chemical Society - Faraday Transactions p. 477 - 484 (1993)

Update date:2022-08-22

Topics:

Authors:

Mohan, H.Mohan, H.

Maity, D. K.Maity, D. K.

Mittal, J. P.Mittal, J. P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/ft9938900477

The transient optical absorption bands formed on reaction of *OH radicals with 1,m-dibromoalkanes and n-alkyl bromides in acidic aqueous solutions have been assigned to intra-, <*>, and inter-molecular, , radical cations, respectively.Depending upon R, these radical cations exhibit an optical absorption band in the 385-450 nm region.Increases in the chain length and electron-releasing power of R results in a red shift of λmax and a decrease in the lifetime.These radical cations are strong oxidants and oxidize various substrates with bimolecular rate constants of the order of 109 dm3 mol-1 s-1.

View More

Products guided by the article

Product name:1,3-Dibromopropane

Cas No:109-64-8

109-64-8

R&D Labs maybe for 109-64-8

Relevant to this article

Hot Product