Tributylarsonium-2,2,3,3,4,4-hexafluorocyclobutane Ylide. Preparation and Cleavage

DOI: 10.1016/S0022-1139(00)82659-7

Source and publish data:

Journal of Fluorine Chemistry p. 413 - 416 (1981)

Update date:2022-08-15

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Authors:

Burton, Donald J.

Valk, Paul D. Vander

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Article abstract of DOI:10.1016/S0022-1139(00)82659-7

F-cyclobutane forms a stable ylide with n-tributylarsine.In contrast to the halogen cleavage of the analogous phophonium ylide, which gives 1,1-dihaloalkanes, the arsonium ylide reacts with bromine and iodine to give the 1-halo-F-cyclobutenes.

Full text of DOI:10.1016/S0022-1139(00)82659-7

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