Journal of the Chemical Society. Perkin transactions II p. 493 - 496 (1983)
Update date:2022-08-16
Topics:
Angeletti, Enrico
Tundo, Pietro
Venturello, Paolo
Rubo, Marco
The alkali-metal halide crystals produced during an organic synthesis carried out under gas-liquid phase-transfer catalysis (g.l.-p.t.c.) conditions grow in an unusual liquid medium by consuming the nucleophile salt; their habit depends on the catalyst used and on the reaction considered.The particular crystal habit, showing a cavity on one face only of the cube or on one corner only of the octahedron, illustrates some aspects of the crystal growth and gives information on g.l.-p.t.c. mechanism.
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