Angewandte Chemie - International Edition p. 351 - 354 (1999)
Update date:2022-08-23
Topics:
Fischer, Achim
Mallat, Tamas
Baiker, Alfons
Enhancements in selectivity by a factor of 4 to 18 were observed in the near critical regions of ammonia during the Co- and Ni-catalyzed synthesis of 1,3-diamino-propanes. These results are attributed to the higher concentration of ammonia at the surface of the catalyst, which favors the amination and suppresses degredation reactions.
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