Journal of Fluorine Chemistry p. 653 - 662 (1987)
Update date:2022-08-10
Topics:
Terjeson, Robin J.
Gard, Gary L.
New fluorinated polymers containing the pentafluorothio group have been prepared from SF5Br and the appropriate fluoroolefin under reaction temperatures of 90+/-5 deg C and autogeneous pressures of up to 90 atmospheres for periods of four days to two weeks.With ethylene, FCH2CH2Br and SF5CH2CH2Br were formed.A new monomer addition product, SF5CF2CF2Br, is also reported for the first time.
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