Palladium(0)-catalyzed reaction of propargylic phosphates with SmI2: A highly regioselective route to the synthesis of allenes and acetylenes

DOI: 10.1016/0040-4039(94)02357-H

Source and publish data:

Tetrahedron Letters p. 907 - 908 (1995)

Update date:2022-08-16

Topics:

Authors:

Mikami Mikami

Mikami, Koichi

Yoshida Yoshida

Yoshida, Akihiro

Matsumoto

Matsumoto, Shoji

Feng Feng

Feng, Feng

Matsumoto

Matsumoto, Youichi

Sugino Sugino

Sugino, Akihiro

Hanamoto

Hanamoto, Takeshi

Inanaga Inanaga

Inanaga, Junji

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Article abstract of DOI:10.1016/0040-4039(94)02357-H

A highly regioselective reaction of propargylic phosphates has been established by using SmI₂ and a Pd(0) catalyst to give allenes and acetylenes in high isolated yields depending on the substrate used.

Full text of DOI:10.1016/0040-4039(94)02357-H

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