Chemistry Letters p. 93 - 96 (1994)
Update date:2022-08-24
Topics:
Chenevert, Robert
Lavoie, Michele
Courchesne, Gabriel
Martin, Richard
We report the first asymmetric synthesis of amidinomycin, an antiviral antibiotic metabolite.Amidinomycin of high enantiomeric purity (ee 91percent) was prepared from norbornylene in 8 steps.The key step is an enzymatic discrimination of enantiotopic groups in meso cis-1,3-dicarbomethoxycyclopentane or in meso cis-cyclopentane-1,3-dicarboxylic acid anhydride.
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