Bulletin of the Chemical Society of Japan p. 353 - 354 (1983)
Update date:2022-08-24
Topics:
Suzuki, Nobutaka
Ayaguchi, Yasuo
Tsukanaka, Tsuneaki
Izawa, Yasuji
A practically homogeneous system of PdCl2 in CH2Cl2 in the presence of polyethylene glycol catalyzed hydrogenation reactions of diphenylethyne (1) and cis-1,2-diphenylethene (2) to 2 and/or 1,2-diphenylethane (4).Under the conditions, the selectivity of the hydrogenation of 1 to 2 against that of 1 to 4 was excellent, compared to that using the Pd/C system.
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