Tetrahedron Letters p. 2783 - 2786 (1990)
Update date:2022-08-11
Topics:
Bergman
Nilsson
Wickberg
1,4-Diketones may conveniently be synthesized by the addition of 2-methylcyclopropenyllithium to N-methoxy-N-methylcarboxamides followed by hydrolysis of intermediate cyclopropyl ketone adducts on silica gel. The new method has been applied to the synthesis of cis-jasmone.
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