Tetrahedron Letters p. 5169 - 5172 (1994)
Update date:2022-08-25
Topics:
McCormick, Frankie A.
Marquardt, Donald J.
An efficient oxidation of methyl and primary side chains of anthracene Diels Alder adducts with KMnO4 is reported. The oxidation leaves the bridgehead methines intact providing Diels-Alder adducts of anthracenecarboxylic acids. Retro Diels-Alder reaction allows for the preparation of the parent anthracenecarboxylic acids.
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