Oxidation of aliphatic side chains in anthracene Diels-Alder adducts

DOI: 10.1016/S0040-4039(00)77055-9

Source and publish data:

Tetrahedron Letters p. 5169 - 5172 (1994)

Update date:2022-08-25

Topics:

Authors:

McCormick, Frankie A.

Marquardt, Donald J.

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Article abstract of DOI:10.1016/S0040-4039(00)77055-9

An efficient oxidation of methyl and primary side chains of anthracene Diels Alder adducts with KMnO₄ is reported. The oxidation leaves the bridgehead methines intact providing Diels-Alder adducts of anthracenecarboxylic acids. Retro Diels-Alder reaction allows for the preparation of the parent anthracenecarboxylic acids.

Full text of DOI:10.1016/S0040-4039(00)77055-9

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