Journal of the Chemical Society. Chemical communications p. 146 - 147 (1987)
Update date:2022-08-10
Topics:
Escaffre, Pascale
Thorez, Alain
Kalck, Philippe
The fast and selective conversion of alkenes into aldehydes can be achieved under mild conditions by using the CO/H2O couple in the presence of the water-soluble complexes Rh2(μ-SBut)2(CO)2(Ls)2, Rh(cod)(Ls)2+ (cod = cyclo-octa-1,5-diene), and RhH(CO)(Ls)3, where Ls is the trisulphonated phosphine, P(m-C6H4SO3Na).
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