Alkene and alkyne oxidative cleavage catalyzed by RuO4 in environmentally acceptable solvents

DOI: 10.1081/SCC-120022466

Source and publish data:

Synthetic Communications p. 2945 - 2951 (2003)

Update date:2022-08-17

Topics:

Authors:

Griffith, William P.

Kwong, Eugene

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Article abstract of DOI:10.1081/SCC-120022466

The application of CCl₄, C₆Hl₂, EtOAc, and Me₂CO as solvents for biphasic systems has been compared for oxidative cleavage of alkenes and alkynes by RuO₄ to carboxylic acids, using the RuCl₃·nH₂O-IO(OH)₅ reagent for which an improved procedure is described. Cyclohexane is an effective and economic replacement for the environmentally unfriendly CCl ₄; acetone and ethyl acetate are less effective.

Full text of DOI:10.1081/SCC-120022466

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