Journal of the Chemical Society. Chemical communications p. 206 - 207 (1991)
Update date:2022-08-30
Topics:
Yaouanc, Jean-Jacques
Bris, Nathalie Le
Gall, Guenaelle Le
Clement, Jean-Claude
Handel, Henri
Abbayes, Herve des
The fac-LCr(CO)3 tridentate complexes of 1,4,7,10-tetraazacyclododecane 1, 1,4,8,11-tetraazacyclotetradecane 2, 1,4,7,10-tetraazadecane 3 and 1,5,8,12-tetraazadodecane 4 have been shown selectively alkylated in high yield at the uncomplexed nitrogen atom, giving rise to mono N-functionalized tetraamines and bis-macrocyclic compounds.
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