Carbohydrate Research p. 83 - 94 (1986)
Update date:2022-08-11
Topics:
Angyal, Stephen J.
Stevens, John D.
Odier, Leon
The rate of protium-deuterium exchange, catalyzed by deuterated Raney nickel in deuterium oxide, in various positions in methyl glycopyranosides and furanosides has been studied.In general, the exchange process is not highly regioselective in these compounds.However, conditions were found under which methyl β-D-fructopyranoside can be selectively labelled on C-5, methyl β-D-fructofuranoside on C-3, and methyl β-D-galactopyranoside on C-3 and C-4.
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