Journal of Organometallic Chemistry p. 75 - 94 (1988)
Update date:2022-08-11
Topics:
Lindner, Ekkehard
Sickinger, Anselm
Wegner, Peter
The (ether-phosphane) ligands R2PCH2(1,4-diox) (1a-c) (R=Ph (a), Mess (b), Cy (c); diox=dioxane residue) and Ph2PCH2(1,3-diox) (2a) are obtained from the corresponding phosphides LiPR2 and 2-chloromethyl-1,4-dioxane and -1,3-dioxane, respectively, at -40 oC in ether.High pressure experiments can provide useful information on conversion and selectivity in the (hydro)carbonylation of methanol, if parameters like educt/catalyst ratio, effect of substituents of the ligands 1a-c, 2a, directed application of cobalt complexes, and composition of catalyst and synthesis gas are varied.The possibility that there is a cobalt-catalyzed (hydro)carbonylation of methanol to acetaldehyde and acetic acid cycle is explored.
View MoreZhejiang Sanmei Chemical Industry Co., Ltd
Contact:86-579-87633213
Address:Huchu Industrial Zone, Qingnian Rd., Wuyi County, Zhejiang Prov., China.
Contact:86-571-85586718
Address:join hands science park,NO.4028 nanhuan road,hanghzou ,zhejiang,china
Shenyang Xinyihan Chemical Technology Co., Ltd.
Contact:+86-18525026267
Address:362, aigongbeijei street 23 , tiexi district,Shenyang, Liaoning, China
Zhejiang Bolaite Technology Co.,Ltd
Contact:+86-0570-6523168 +86-0570-6523150
Address:No.5 YinKeng Road Kaihua Industrial Park(Chengguan Town) Zhejiang Prov.
Changzhou Kingyo Chemical Corporation Ltd.
website:http://www.kingyochem.com
Contact:+86-519-85105717
Address:19# Wuqing North Road, Changzhou , Jiangsu, China
Doi:10.1039/c9nj05956c
(2020)Doi:10.1016/S0040-4039(98)02410-1
(1999)Doi:10.1007/BF00799229
(1982)Doi:10.1016/j.tet.2007.11.061
(2008)Doi:10.1016/S0022-328X(01)01293-1
(2002)Doi:10.1246/bcsj.54.2908
(1981)