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Dynamic kinetic resolution of cyclic β-ketoesters with preformed or prepared in situ chiral diphosphine-ruthenium (II) catalysts

DOI: 10.1016/S0040-4039(00)60727-X

Source and publish data:

Tetrahedron Letters p. 4559 - 4562 (1994)

Update date:2022-08-31

Topics:

Authors:

GenetGenet

PfisterPfister

Ratovelomanana-VidalRatovelomanana-Vidal

PinelPinel

LaffitteLaffitte

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Article abstract of DOI:10.1016/S0040-4039(00)60727-X

The reduction of racemic β-keto esters having the tetralone structure by chiral ruthenium(II) catalysts is realized with an ideal kinetic dynamic resolution. Remarkably, high anti selectivity approaching 100% and enantioselectivity (up to 97%) using atrop

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Full text of DOI:10.1016/S0040-4039(00)60727-X

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