LES (TRIMETHYLSILYL)BICYCLO-ALCENES, NOUVEAUX SILYLCYCLOPROPANES BICYCLIQUES FONCTIONNELS

DOI: 10.1002/recl.19881070322

Source and publish data:

Recueil des Travaux Chimiques des Pays-Bas p. 216 - 225 (1988)

Update date:2022-08-03

Topics:

Authors:

Grignon-Dubois, M.

Dunogues, J.

Ahra, M.

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Article abstract of DOI:10.1002/recl.19881070322

A convenient synthesis of new silylbicyclo-alkenes is reported involving a facile and rapid process and giving both endo and exo monosilyl isomers as well as gem-disilyl derivatives.The behaviour of these species towards acids has been investigated.Both the size of the large ring and the double-bond position play a role in the regiochemistry of the electrophilic attack.These results bring to ligth new perspectives for functionalization of cyclololefins via cyclopropanation.

Full text of DOI:10.1002/recl.19881070322

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