Determination of Metal-Hydride and Metal-Ligand (L = CO, N2) Bond Energies Using Photoacoustic Calorimetry

DOI: 10.1021/ja00058a043

Source and publish data:

Journal of the American Chemical Society p. 1921 - 1925 (1993)

Update date:2022-08-11

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Authors:

Belt, Simon T.

Scaiano, J. C.

Whittlesey, Michael K.

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Article abstract of DOI:10.1021/ja00058a043

Photoacoustic calorimetry has been used to determine the M-H mean bond dissociation energies in Ru(dmpe)2H2 (dmpe = Me2PCH2CH2PMe2) and H2IrCl(CO)(PPh3)2 (63.5 +/- 2.0 and 64.0 +/- 1.0 kcal mol^-1, respectively).The quantum yield for loss of H2

Full text of DOI:10.1021/ja00058a043

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