Journal of the American Oil Chemists' Society p. 333 - 336 (1996)
Update date:2022-08-23
Topics:
Choo, Yuen-May
Ooi, Kay-Eng
Ooi, Ing-Hong
Tan, Daniel D. H.
10,11-Dioctyleicosane, a star-shaped hydrocarbon, has been successfully synthesized from 9-octadecene (a product from metathesis of methyl oleate or ethyl oleate) through dimerization followed by hydrogenation.The product was determined by 13C nuclear magnetic resonance spectroscopic and gas chromatography/mass spectrometric techniques.This hydrocarbon likely exhibits lubricating properties that can be used as high-performance functional fluids in automotive lubrication.We also report the presence of a novel product, a trimer that was formed during the synthesis. - Key words: Diethyl 9-octadecenedioate; 10,11-dioctyl eicosane; ethyl and methyl oleates; metathesis; 9-octadecene; palm oil; star-shaped hydrocarbon.
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