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Selective Hydroformylation with a Recoverable Dirhodium μ-Thiolato Complex

DOI: 10.1039/c39890001056

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1056 - 1057 (1989)

Update date:2022-08-11

Topics:

Authors:

Bayon, J. C.Bayon, J. C.

Real, J.Real, J.

Claver, C.Claver, C.

Polo, A.Polo, A.

Ruiz, A.Ruiz, A.

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Article abstract of DOI:10.1039/c39890001056

The dimeric precursor complex 2(cod)2>, (cod=cyclo-octa-1,5-diene), with PPh3 catalyses the hydroformylation of hex-1-ene, under mild conditions, into heptanals with high yields and selectivities; owing to the presence of the amine group the rhodium catalyst can be quantitatively recovered from the reaction mixture by adding dilute H2SO4, and reused without loss of activity.

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Product name:Heptanal

Cas No:111-71-7

111-71-7

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