Selective Hydroformylation with a Recoverable Dirhodium μ-Thiolato Complex

DOI: 10.1039/c39890001056

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1056 - 1057 (1989)

Update date:2022-08-11

Topics:

Authors:

Bayon, J. C.

Real, J.

Claver, C.

Polo, A.

Ruiz, A.

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Article abstract of DOI:10.1039/c39890001056

The dimeric precursor complex 2(cod)2>, (cod=cyclo-octa-1,5-diene), with PPh3 catalyses the hydroformylation of hex-1-ene, under mild conditions, into heptanals with high yields and selectivities; owing to the presence of the amine group the rhodium catalyst can be quantitatively recovered from the reaction mixture by adding dilute H2SO4, and reused without loss of activity.

Full text of DOI:10.1039/c39890001056

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