Different stereochemistry for the reduction of trifluoromethyl ketones and methyl ketones catalyzed by alcohol dehydrogenase from Geotrichum

DOI: 10.1016/0040-4039(96)01211-7

Source and publish data:

Tetrahedron Letters p. 5727 - 5730 (1996)

Update date:2022-08-16

Topics:

Authors:

Nakamura, Kaoru

Matsuda, Tomoko

Itoh, Toshiyuki

Ohno, Atsuyoshi

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Article abstract of DOI:10.1016/0040-4039(96)01211-7

Reduction of trifluoromethyl ketones by a crude alcohol dehydrogenase from Geotrichum affords (S)-trifluoromethyl carbinols in excellent ee, whereas the reduction of methyl ketones gives the corresponding alcohols of the opposite configuration in excellent ee.

Full text of DOI:10.1016/0040-4039(96)01211-7

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