Journal of the American Chemical Society p. 509 - 511 (1988)
Update date:2022-08-29
Topics:
Kawamura, Shinichi
Tsutsui, Tetsuo
Saito, Shogo
Murao, Yuko
Kina, Kenyu
The photochromic behavior of an amphiphilic salicylideneaniline derivative, N-(4-dodecoxysalicylidene)-4-carboxyaniline (DSA), incorporated in a Langmuir-Blodgett film was studied.DSA formed a stable and condensed monolayer at an air-water interface, and the monolayer was transferred on quartz substrates.The built-up multilayer was found to possess a highly ordered and densely packed structure.Reversible photochromism of a salicylideneaniline group was observed in built-up DSA films on repeating irradiation with UV light.The rate of the thermal decoloration was proved to be suppressed by the ordered molecular environment in the multilayer.
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