Tetrahedron Asymmetry p. 3585 - 3589 (1997)
Update date:2022-08-17
Topics:
Kang, Fu-An
Yin, Cheng-Lie
Some new chemistry of the chiral nitronic acid and nitronic esters is described. Conversions with retention of configuration are found among the chiral nitronic acid, oxime, nitronic esters and O-alkyloximes. α,β- Elimination reactions of nitronic esters are observed for the first time. Novel and enantiopure chiral bisheterocyclic compounds are obtained via highly diastereoselective 1,3-dipolar cycloaddition of the chiral nitronic esters with ethyl acrylate.
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Doi:10.1107/S0567740877014332
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